Please use this identifier to cite or link to this item: https://cris.library.msu.ac.zw//handle/11408/3851
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dc.contributor.authorDube, Edith-
dc.contributor.authorOluwole, David, O-
dc.contributor.authorNyokong, Tebello-
dc.date.accessioned2020-10-23T11:30:34Z-
dc.date.available2020-10-23T11:30:34Z-
dc.date.issued2018-
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/full/10.1111/php.12879-
dc.identifier.urihttp://hdl.handle.net/11408/3851-
dc.description.abstractThis work reports on the synthesis of tetrakis‐[(thiophineethoxy) phthalocyaninato] indium(II) chloride (3). The photophysical behavior of complex 3 was compared to that of the Zn derivative (tetrakis‐[(thiophineethoxy) phthalocyaninato] zinc(II) (complex 2)). The compounds were interacted with gold‐speckled silica (GSS) nanoparticles via Au–S self assembly to afford the conjugates (2–GSS and 3–GSS). The photophysicochemical behavior of the compounds and their conjugates were assessed. The conjugates afforded a decrease in fluorescence quantum yields and lifetimes with improved triplet and singlet oxygen quantum yields in comparison with complexes 2 and 3 alone. The complexes and their conjugates could serve as good candidates for photodynamic therapy.en_US
dc.language.isoenen_US
dc.publisherPhotochemistry and Photobiologyen_US
dc.relation.ispartofseriesVol.94 , Issue 3, 521 - 531;-
dc.subjectPhotophysical and Photochemical Propertiesen_US
dc.subjectthiopheneethoxyen_US
dc.subjectmetallophthalocyaninesen_US
dc.subjectgold‐speckled silica nanoparticlesen_US
dc.titleImproved Photophysical and Photochemical Properties of Thiopheneethoxy Substituted Metallophthalocyanines on Immobilization onto Gold-speckled Silica Nanoparticlesen_US
dc.typeArticleen_US
item.grantfulltextopen-
item.languageiso639-1en-
item.fulltextWith Fulltext-
item.openairetypeArticle-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
Appears in Collections:Research Papers
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